Addition Polymers
This is part of the HSC Chemistry course under the topic Polymers. There are two types of polymers: addition and condensation polymers.
HSC Chemistry Syllabus
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model and compare the structure, properties and uses of addition polymers of ethylene and related monomers, for example:
– polyethylene (PE)
– polyvinyl chloride (PVC)
– polystyrene (PS)
– polytetrafluoroethylene (PTFE) (ACSCH136)
Addition Polymers: HDPE, LDPE, PVC, PS and PTFE
This video introduces the concept of addition polymers. The video discusses the structure, properties and uses of various addition polymers including:
- Polyethylene (PE)
- Polyvinylchloride (PVC)
- Polystyrene (PS)
- Polytetrafluoroethylene (PTFE)
How are Addition Polymers Produced?
- Addition polymers are produced using monomers with double carbon-to-carbon bonds (C=C).
Polymerisation of ethylene produces polyethylene
- Reactive C=C of alkene molecules can ‘open up’ to form single carbon-carbon bonds with other alkene molecules. This results in the formation of a long, saturated polymer chain.
Step 1: Initiation
- An initiator molecule e.g. hydrogen peroxide (H2O2) produces free radical OH species with a highly reactive unpaired electron.
- The unpaired electron forms a new covalent bond with one of the electrons in the C=C bond in the monomer. This produces another radical molecule with an unpaired electron that was formerly in the C=C bond.
Step 2: Elongation
- The radical molecule formed in initiation is able to react with another monomer via the same mechanism, that is the unpaired electron forms a covalent bond with one of the electrons in the C=C bond.
- This reaction joins the two organic molecules to produce a larger molecule that also contains an unpaired electron.
- As the reaction between the radical molecule and monomers continues, the molecule grows in length
Step 3: Termination
- Elongation of the molecule stops when two radical molecules (with unpaired electrons) react to form a covalent bond. This terminates the polymerisation as the product no longer has an unpaired electron.
- Termination can occur with hydroxyl radical molecules produced from hydrogen peroxide or another large polymer that has an unpaired electron.
- Two relatively large radical molecules react to produce a final product (polymer)
High-density Polyethylene (HDPE)
- Structure: HDPE consists of straight, linear chains of polyethylene with no or minimal branching.
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Uses |
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Low-density Polyethylene (LDPE)
- Structure: polyethylene chains with numerous branches.
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Uses |
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Polyvinyl chloride (PVC)
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Properties |
Uses |
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Rigid PVC
Flexible PVC
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Polystyrene (PS)
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Properties of PS
Uses of PS
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Polytetrafluoroethylene (PTFE)
- Structure: PTFE is produced from polymerisation of tetrafluoroethene. Each monomer is essentially an ethene molecule with all 4 hydrogen atoms replaced by fluorine atoms.
Properties of PTFE
Uses of PTFE
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